In this study, natural organic matter (NOM) characteristics were investigated over three years of monthly monitoring
to determine the effect of seasonal variations on NOM levels from source to tap. Liquid chromatography
with organic carbon detection (LC-OCD)was used to determine NOMcharacteristics and the level of reduction of
biodegradable dissolved organic carbon (BDOC). The average dissolved organic matter concentration in the
source water (Lake Paldang, Korea) was not significantly different between summer and winter. However, the
distribution of NOM components, such as biopolymers, building blocks, low molecular weight (MW) neutrals
and acids, identified by LC-OCD, varied seasonally.While highMWNOM was preferentially removed by coagulation/
sedimentation/rapid sand filtration (CSR), no seasonal effects were observed on the removal of high MW
NOM. CSR and biological activated carbon (BAC) filtration showed a better efficiency of BDOC removal in winter
and summer, respectively. High concentrations of chlorine used in the treatment plants in summer resulted in
10% higher DOC concentrations during disinfection. Overall NOM removal efficiencies from source to tap were
45% and 35% for summer andwinter, respectively. Principal component analysis also indicated that seasonal variations
(principal component 1) showed the strongest positive correlationwith the overall performance ofwater
treatment. The long-term monitoring of drinking water treatment processes showed that seasonal variations
were important factors affecting NOM characteristics during water treatment.