EVALUATION OF MIXED OXIDANTS GENERATED BY ELECTRO-CHEMICAL METHOD |
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학술지명 Efficient 2007
저자 이두진,임재림,이경혁,김성수
발표일 2007-05-21
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Mixed oxidants produced by means of electro-chemical method were evaluated to confirm the presence of oxidants other than free chlorine. Inactivation rate of B. subtilis spore on the mixed oxidants were similar with that on free chlorine. Activation energy of mixed oxidants and free chlorine for B. subtilis spore inactivation at pH 8.3 were determined as 30.8 kJ?mol-1, 34.7 kJ?mol-1 respectively. UV absorption spectrum of both free chlorine and mixed oxidants were compared. Molar extinction coefficients of free chlorine and mixed oxidants at 292nm, which is maximum absorption wavelength of OCl- were 357 M-1 cm-1, 377 M-1 cm-1, respectively. Disinfectant decay rate and formation rate of THM on sand filtration effluent at Suji WTP were compared. The disinfectant decay rate followed first order reaction for both mixed oxidants and chlorine. In order to evaluate the effect of secondary disinfection, the decay rate of chlorine followed by mixed oxidants was evaluated compared with chlorine secondary disinfection. The formation rate of THM on both mixed oxidants and chlorine show insignificant difference. In consequence, it resulted that most of oxidants in mixed oxidants is hypochlorite. |