D댐수를 이용한 정밀여과 공정에서 막오염 특성 및 최적화학세정방법 조사 |
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학술지명 대한상하수도학회
저자 박상훈,채선하,이병구,임재림,김충환,박민구
발표일 2007-10-01
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The purposes of this study were to find the main foulant of membrane and the optimal chemical cleaning method for MF(microfiltration) drinking water treatment system using D dam water as water source. The MF pilot plant which can treat maximum 500 m3/d consisted of 3 racks and was operated for 10 months under various operation conditions. After 10 months operation, 1st and 2nd rack of membrane pilot plant system were cleaned chemically and the degree of the restoration of the fouled membrane in terms of the pure water flux was determined. Inorganic compounds which contained in chemical cleaning waste was analyzed by Inductively Coupled Plasma(ICP). One membrane module for 3rd rack was disjointed and membrane fouling materials, especially inorganic compounds were investigated by Electron Probe Microanlysis(EPMA) to elucidate the reason of TMP increase. And also, the various chemical reagents(1N HCl or H2SO4, oxalic acid as acid and 0.3% NaOCl as alkali) were tested by combination of acid and alkali to determine the optimal chemical cleaning method for the MF system using micro-modules manufactured using the disjointed module. It was verified that the inside and outside of membrane module was colorized with black. As a result of the quantitative and semi-qualitative analysis of membrane foulant by ICP, most of inorganic foulant was manganese which is hard to remove by inorganic acid such as HCl. Especially, it was observed by EPMA that Mn was attached more seriously in inside surface of membrane than in outside surface of that. It was supposed that Mn fouling in inside surface of membrane might be caused by the oxidation of soluble manganese (Mn(II)) to insoluble manganese(MnO2) by chlorine containing in backwashing water. The optimal cleaning method for the removal of manganese fouling was consecutive cleaning with the mixture of 1N HCl and 1% of oxalic acid, 0.3% NaOCl, and 1N HCl showing 91% of the restoration of the fouled membrane. |